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Ternary Liquid−Liquid(−Liquid) Equilibria of Aniline + Cyclohexylamine + Water, Aniline + Cyclohexylamine + Octane, Aniline + Water + Toluene, and Aniline + Water + Octane
- Source :
- Journal of Chemical & Engineering Data. 51:1009-1014
- Publication Year :
- 2006
- Publisher :
- American Chemical Society (ACS), 2006.
-
Abstract
- Four ternary liquid−liquid(−liquid) equilibria in the systems aniline + cyclohexylamine (CHA) + water, aniline + CHA + octane, aniline + water + octane, and aniline + water + toluene under atmospheric pressure at (298.15 and 333.15) K are reported. The measurements were carried out by turbidity titration, gas−liquid chromatography analyses, Karl Fischer, and potentiometric titration. Predictions of the NRTL and UNIQUAC Gibbs energy models are shown based only on binary parameters of simultaneous fitting of available vapor−liquid equilibria and liquid−liquid equilibria data. In this context P−x data were measured for the system aniline + octane at 383.15 K.
Details
- ISSN :
- 15205134 and 00219568
- Volume :
- 51
- Database :
- OpenAIRE
- Journal :
- Journal of Chemical & Engineering Data
- Accession number :
- edsair.doi...........5443eb9ba0df3e3b97457897a8229290
- Full Text :
- https://doi.org/10.1021/je0505366