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Ternary Liquid−Liquid(−Liquid) Equilibria of Aniline + Cyclohexylamine + Water, Aniline + Cyclohexylamine + Octane, Aniline + Water + Toluene, and Aniline + Water + Octane

Authors :
René Meinhardt
Jürgen Schmelzer
Mandy Klauck
and Roland Schumann
Andreas Grenner
Source :
Journal of Chemical & Engineering Data. 51:1009-1014
Publication Year :
2006
Publisher :
American Chemical Society (ACS), 2006.

Abstract

Four ternary liquid−liquid(−liquid) equilibria in the systems aniline + cyclohexylamine (CHA) + water, aniline + CHA + octane, aniline + water + octane, and aniline + water + toluene under atmospheric pressure at (298.15 and 333.15) K are reported. The measurements were carried out by turbidity titration, gas−liquid chromatography analyses, Karl Fischer, and potentiometric titration. Predictions of the NRTL and UNIQUAC Gibbs energy models are shown based only on binary parameters of simultaneous fitting of available vapor−liquid equilibria and liquid−liquid equilibria data. In this context P−x data were measured for the system aniline + octane at 383.15 K.

Details

ISSN :
15205134 and 00219568
Volume :
51
Database :
OpenAIRE
Journal :
Journal of Chemical & Engineering Data
Accession number :
edsair.doi...........5443eb9ba0df3e3b97457897a8229290
Full Text :
https://doi.org/10.1021/je0505366