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Hydrosilylation of olefins over rhodium complex anchored over thioether-functionalized MCM-41
- Source :
- Chinese Chemical Letters. 21:1310-1313
- Publication Year :
- 2010
- Publisher :
- Elsevier BV, 2010.
-
Abstract
- The hydrosilylation of alkenes with triethoxysilane has been achieved at 120 °C in the presence of 0.01 mol% of thioether-functionalized MCM-41 anchored rhodium complex, affording the corresponding addition products in 68–91% yields. This supported rhodium complex can be reused several times without noticeable loss of activity. Our system not only solves the basic problems of catalyst separation and recovery, but also avoids the use of phosphine ligands.
Details
- ISSN :
- 10018417
- Volume :
- 21
- Database :
- OpenAIRE
- Journal :
- Chinese Chemical Letters
- Accession number :
- edsair.doi...........54c62551d90d648faa1408bb7d3605d4