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Divalent cobalt, zinc, and copper coordination polymers based on a new bifunctional ligand: Syntheses, crystal structures, and properties
- Source :
- Inorganic Chemistry Communications. 39:106-109
- Publication Year :
- 2014
- Publisher :
- Elsevier BV, 2014.
-
Abstract
- Three new coordination polymers, namely, [ML(H2O)]n (M = Co (1), Zn (2)) and [CuL(DMF)]n (3), have been hydrothermally synthesized through the reaction of bifunctional ligand 5-((2-methyl-1H-imidazol-1-yl)methyl)benzene-1,3-dioic acid (H2L) with divalent cobalt, zinc and copper salts, and structurally characterized by elemental analysis, IR and X-ray diffraction. Both complexes 1 and 2 are two-fold interpenetration 3D frameworks. Complex 3 exhibits (3,6)-connected framework with (4.62)2(42.610.83) topology. Furthermore, UV–vis absorption spectra and powder X-ray diffraction (PXRD) were investigated as well.
Details
- ISSN :
- 13877003
- Volume :
- 39
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........578d817e47e455cc41396b127e04e98e