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Synthesis, structure, electrical and magnetic properties of (BEDT-TTF)2[3,3′-Fe(1,2-C2B9H11)2]
- Source :
- Inorganic Chemistry Communications. 15:106-108
- Publication Year :
- 2012
- Publisher :
- Elsevier BV, 2012.
-
Abstract
- New radical cation salt of bis(ethylenedithio)tetrathiafulvalenium and iron bis(dicarbollide) [BEDT-TTF] 2 [3,3′-Fe(1,2-C 2 B 9 H 11 ) 2 ] ( 1 ) has been synthesized. The crystal structure of 1 has been determined by single-crystal X-ray diffraction method found to be isostructural to the known Co and Cr analogues. The electric conductivity measurement in the range of 110 ÷ 296 К shows that 1 is semiconductor with the room temperature conductivity σ 293 = 1.5 × 10 −2 Ω −1 cm −1 , that is higher than in the Cr analogue and lower than in the Co analogue. The measurement of magnetic susceptibility in the range of 2 ÷ 300 K revealed that 1 is paramagnetic with the absence of significant interactions between the organic radical cations and the paramagnetic anions.
- Subjects :
- Chemistry
business.industry
Inorganic chemistry
Crystal structure
Conductivity
Magnetic susceptibility
Inorganic Chemistry
Crystallography
Paramagnetism
Semiconductor
Radical ion
Electrical resistivity and conductivity
Materials Chemistry
Physical and Theoretical Chemistry
Isostructural
business
Subjects
Details
- ISSN :
- 13877003
- Volume :
- 15
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........57b8144870ee9f2cc53c271fa832e7e8
- Full Text :
- https://doi.org/10.1016/j.inoche.2011.10.002