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Synthesis, structure, electrical and magnetic properties of (BEDT-TTF)2[3,3′-Fe(1,2-C2B9H11)2]

Authors :
Alexander Feher
Igor B. Sivaev
Irina D. Kosenko
Marcela Kajňaková
Olga N. Kazheva
Lev I. Buravov
Vladimir A. Starodub
Oleg A. Dyachenko
Vladimir I. Bregadze
Grigorii G. Alexandrov
Andrey V. Kravchenko
Irina A. Lobanova
Source :
Inorganic Chemistry Communications. 15:106-108
Publication Year :
2012
Publisher :
Elsevier BV, 2012.

Abstract

New radical cation salt of bis(ethylenedithio)tetrathiafulvalenium and iron bis(dicarbollide) [BEDT-TTF] 2 [3,3′-Fe(1,2-C 2 B 9 H 11 ) 2 ] ( 1 ) has been synthesized. The crystal structure of 1 has been determined by single-crystal X-ray diffraction method found to be isostructural to the known Co and Cr analogues. The electric conductivity measurement in the range of 110 ÷ 296 К shows that 1 is semiconductor with the room temperature conductivity σ 293 = 1.5 × 10 −2 Ω −1 cm −1 , that is higher than in the Cr analogue and lower than in the Co analogue. The measurement of magnetic susceptibility in the range of 2 ÷ 300 K revealed that 1 is paramagnetic with the absence of significant interactions between the organic radical cations and the paramagnetic anions.

Details

ISSN :
13877003
Volume :
15
Database :
OpenAIRE
Journal :
Inorganic Chemistry Communications
Accession number :
edsair.doi...........57b8144870ee9f2cc53c271fa832e7e8
Full Text :
https://doi.org/10.1016/j.inoche.2011.10.002