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When phosphoryl azide meets mechanochemistry: clean, rapid, and efficient synthesis of phosphoryl amides under B(C6F5)3 catalysis in a ball mill

Authors :
Xin-Hua Peng
Zhuo Li
Ze-Lin Wang
Lin-Yu Jiao
Nan Jia
Source :
Catalysis Science & Technology. 11:6659-6665
Publication Year :
2021
Publisher :
Royal Society of Chemistry (RSC), 2021.

Abstract

We described herein the first example associated with B(C6F5)3-catalyzed preparation of phosphoryl amides under mechanochemical conditions. In this novel system, the combination of energetic reagents with an energetic mechanochemical process enabled the reaction to proceed under very mild conditions and accelerated the desired nucleophilic attack on the phosphorus center.

Details

ISSN :
20444761 and 20444753
Volume :
11
Database :
OpenAIRE
Journal :
Catalysis Science & Technology
Accession number :
edsair.doi...........58ed148f849f84177d42feff73549711