Ferroelastic properties and compressive stress-strain response of bismuth titanate based ferroelectrics

Ferroelectric materials have been widely studied for applications in numerous devices due to their controllable ferroelectric/ferroelastic properties under electric field or mechanical stress. Recently, a type of bismuth layer-structured ferroelectrics, W/Cr co-doped BIT ceramics, has attracted much attention due to its high Curie temperature, large spontaneous polarization, and particularly enhanced ferroelectric properties. Nevertheless, as a significant consideration for the reliability and durability of devices, the mechanical properties associated with ferroelastic behaviors of this type of ceramics are generally ignored. In this study, a type of W/Cr co-doped BIT ceramics with optimal chemical composition of Bi4Ti2·95W0·05O12.05+0.2 wt% Cr2O3 (BTWC) was synthesized via the solid-reaction technology. Ferroelastic domain structures and ferroelastic switching behaviors together with mechanical failure properties of the sintered ceramics were investigated in details. PFM observations reveal the existence of pseudo-90° and -180° ferroelastic domain structures in BTWC ceramics. The nonlinear deformation of stress-strain curve originates from ferroelastic domain switching induced by mechanical stress of sufficient magnitude. Moreover, the ferroelastic switching plays a significant role in improving the fracture toughness of BTWC ceramics. Additionally, the ceramics sintered at higher temperature are expected to exhibit a better ferroelastic switching behavior yet lower failure stress. The work can provide design consideration of loading conditions for practical applications of BTWC ceramics.