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Bromination of ketones with the systems H2O2-LiBr-CeIII and H2O2-LiBr-CeIV

Authors :
G. I. Nikishin
N. I. Kapustina
L. L. Sokova
Source :
Russian Chemical Bulletin. 62:1214-1217
Publication Year :
2013
Publisher :
Springer Science and Business Media LLC, 2013.

Abstract

A new method for the synthesis of α-bromoketones was suggested. The C5-C11 linear and branched ketones in the reaction with the systems H2O2-LiBr-CeIII and H2O2-LiBr-CeIV in acetonitrile were brominated at α-position. The reaction is highly selective.

Subjects

Subjects :
chemistry.chemical_compound
Chemistry
Lithium bromide
Organic chemistry
Halogenation
General Chemistry
Hydrogen peroxide
Highly selective
Acetonitrile

Details

ISSN :
15739171 and 10665285
Volume :
62
Database :
OpenAIRE
Journal :
Russian Chemical Bulletin
Accession number :
edsair.doi...........59ee23f4ade67a718a4d82ad6e2cf820
Full Text :
https://doi.org/10.1007/s11172-013-0166-2
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