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A magnesium(II) complex of 1,10-phenanthroline-2,9-dicarboxylate

Authors :
Shim Sung Lee
Il Yoon
Joobeom Seo
Yoon Hee Lee
Ki-Min Park
Source :
Acta Crystallographica Section E Structure Reports Online. 57:m154-m156
Publication Year :
2001
Publisher :
International Union of Crystallography (IUCr), 2001.

Abstract

The title compound, tri­aqua(1,10-phenanthroline-2,9-di­car­box­yl­ato)­magnesium(II) dihydrate, [Mg(PDA)(H2O)3]·2H2O, (H2PDA is 1,10-phenanthroline-2,9-di­carboxyl­ic acid, C14H8N2O4) has twofold crystallographic symmetry. The Mg atom is in a distorted pentagonal bipyramidal coordination environment with two N atoms and two O atoms from PDA and one O atom from a water mol­ecule forming the pentagonal plane, and two O atoms from two water mol­ecules occupying axial positions. The crystal structure comprises an infinite two-dimensional network of hydrogen-bonded mol­ecules.

Details

ISSN :
16005368
Volume :
57
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........5dd038d627eb6771703df48158dbf576
Full Text :
https://doi.org/10.1107/s1600536801004317