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The Synthesis of SomeN,N-Dialkylselenocarbamate Complexes of Tin(IV), and Their Infrared and PMR Spectra
- Source :
- Bulletin of the Chemical Society of Japan. 46:2136-2139
- Publication Year :
- 1973
- Publisher :
- The Chemical Society of Japan, 1973.
-
Abstract
- Several N,N-dialkylselenocarbamate complexes of tin(IV), (CH3)2Sn[OSeCNR2]2 (1), (CH3)2ClSn[OSeCNR2] (2) (R=CH3 and C2H5) and (CH3)3Sn[OSeCN(CH3)2] (3), have been prepared, and their infrared and proton magnetic resonance spectra have been examined. The results indicate that in 1 and 2 the selenocarbamate ligands are coordinated to the tin atom in a bidentate manner, although the coordination of the oxygen atom is weak. On the other hand, 3 has a tetra-coordinate tin with a free carbonyl bond. The configurations of these complexes are discussed and compared with those of the corresponding thio-, dithio-, diseleno-, and thioselenocarbamate complexes of tin(IV).
Details
- ISSN :
- 13480634 and 00092673
- Volume :
- 46
- Database :
- OpenAIRE
- Journal :
- Bulletin of the Chemical Society of Japan
- Accession number :
- edsair.doi...........5ee400ece090d2580df8516ea9ff8aeb