Fixation of molecular nitrogen by rare-earth metal compounds

Authors :: Alexander A. Trifonov
M. A. Ilatovskaya
Mikhail N. Bochkarev
G. A. Razuvaev
Vladimir B. Shur
Source :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 35:1726-1728
Publication Year :: 1986
Publisher :: Springer Science and Business Media LLC, 1986.
Abstract: The treatment of Cp2Yb, Cp3Sm, CeCl3, Cp3Ce, and Cp3Eu·THF with excess naphthalenesodium in THF gives systems capable of reducing molecular nitrogen at 20°C and atmospheric pressure with the formation of ammonia after hydrolysis.

Subjects :: Atmospheric pressure
Inorganic chemistry
chemistry.chemical_element
General Chemistry
Photochemistry
Decomposition
Nitrogen
Catalysis
Hydrolysis
Ammonia
chemistry.chemical_compound
chemistry
Nitrogen fixation
Solvolysis

ISSN :: 15739171 and 05685230
Volume :: 35
Database :: OpenAIRE
Journal :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Accession number :: edsair.doi...........601e79f642530042e123c15707d79ac7
Full Text :: https://doi.org/10.1007/bf00954625