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A new pseudo Keggin-type polyvanadate : hydrothermal synthesis and crystal structure
- Source :
- Inorganic Chemistry Communications. 8:592-595
- Publication Year :
- 2005
- Publisher :
- Elsevier BV, 2005.
-
Abstract
- A new pseudo Keggin-type polyvanadate ( NH 4 ) 4 [ H 12 V 12 V O 36 ( V IV O 4 ) ] · 11 H 2 O (1) has been synthesized under hydrothermal condition. The polyoxoanion [H12V13O40]4− of 1 exhibits a classical α-Keggin-type structure, which consists of 12 {VO6} octahedra and a central {VO4} tetrahedron. It is the first pseudo Keggin-type polyvanadate species with mixed VIV/VV metal centers structurally characterized by single-crystal X-ray diffraction hitherto.
Details
- ISSN :
- 13877003
- Volume :
- 8
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........627486421c56aad560ae4d601feccd57
- Full Text :
- https://doi.org/10.1016/j.inoche.2005.03.020