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ChemInform Abstract: γ-Selectivity in the Ceric Ammonium Nitrate Promoted Oxidative Addition of Silyl Dienol Ethers to Silyl Enol Ethers

Authors :
David Latini
Renzo Ruzziconi
Anna Belli Paolobelli
Source :
ChemInform. 24
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

Trimethylsilyl dienol ethers are easily oxidized by ceric ammonium nitrate to give α-carbonylallyl radicals which are able to add to enolic carbon-carbon double bonds with very high γ regioselectivity, allowing the method to be applied to the synthesis of 6-oxo-α,β-unsaturated carbonyl compounds.

Details

ISSN :
09317597
Volume :
24
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........62aa52db958bea0a973fdfb7a5233b0f
Full Text :
https://doi.org/10.1002/chin.199332066