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ChemInform Abstract: γ-Selectivity in the Ceric Ammonium Nitrate Promoted Oxidative Addition of Silyl Dienol Ethers to Silyl Enol Ethers
- Source :
- ChemInform. 24
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- Trimethylsilyl dienol ethers are easily oxidized by ceric ammonium nitrate to give α-carbonylallyl radicals which are able to add to enolic carbon-carbon double bonds with very high γ regioselectivity, allowing the method to be applied to the synthesis of 6-oxo-α,β-unsaturated carbonyl compounds.
Details
- ISSN :
- 09317597
- Volume :
- 24
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........62aa52db958bea0a973fdfb7a5233b0f
- Full Text :
- https://doi.org/10.1002/chin.199332066