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Crystal structure of diethyl-5-(2-(1-(4-bromophenyl)ethylidene)hydrazinyl)-3-methyl-1,2-dihydro-[1,1′-diphenyl]-2,6-dicarboxylate
- Source :
- Journal of Structural Chemistry. 56:1209-1211
- Publication Year :
- 2015
- Publisher :
- Pleiades Publishing Ltd, 2015.
-
Abstract
- The reaction of diethyl-5-methyl-3-oxo-1,2,3,6-tetrahydro-[1,1′-diphenyl]-2,6-dicarboxylate with (1-(4-bromophenyl)ethylidene)hydrazine is conducted, and the crystal structure of the product of this reaction (diethyl-5-(2-(1-(4-bromophenyl)ethylidene)hydrazinyl)-3-methyl-1,2-dihydro-[1,1′-diphenyl]-2,6-dicarboxylate) is determined by single crystal X-ray diffraction. The conformation of the cyclohexadiene ring in the form of a strongly distorted half-chair is determined based on the X-ray diffraction data. The presence of the intramolecular hydrogen bond of the N–H…O=C type is noted.
Details
- ISSN :
- 15738779 and 00224766
- Volume :
- 56
- Database :
- OpenAIRE
- Journal :
- Journal of Structural Chemistry
- Accession number :
- edsair.doi...........6789dfcf60bb26d0c8a49d63bb465d41