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New chiral allylaminosilanes and their use in asymmetric Sakurai reactions
- Source :
- Tetrahedron: Asymmetry. 9:2979-2981
- Publication Year :
- 1998
- Publisher :
- Elsevier BV, 1998.
-
Abstract
- The new allylaminosilanes 2a – c , derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl 4 to give homoallylic alcohols 4a – b with enantiomeric excesses of up to 30%.
Details
- ISSN :
- 09574166
- Volume :
- 9
- Database :
- OpenAIRE
- Journal :
- Tetrahedron: Asymmetry
- Accession number :
- edsair.doi...........67b53f4e65961777b02577e49f3a2067
- Full Text :
- https://doi.org/10.1016/s0957-4166(98)00327-9