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[Untitled]

Authors :
F. Z. Galin
Kukovinets Olga S
V. G. Kasradze
Leonid V. Spirikhin
M. A. Klimkin
Source :
Russian Chemical Bulletin. 51:1765-1767
Publication Year :
2002
Publisher :
Springer Science and Business Media LLC, 2002.

Abstract

Heating of (1S,3S)-3-acetoxymethyl-1-(2-acetoxyvinyl)-2,2-dimethylcyclopropane with bromoform under phase-transfer catalysis affords dibromocyclopropane viaaddition of dibromocarbene to the double bond. In an analogous reaction with chloroform, the trichloromethyl anion adds to the double bond in the α-position with respect to the acetoxy group.

Details

ISSN :
10665285
Volume :
51
Database :
OpenAIRE
Journal :
Russian Chemical Bulletin
Accession number :
edsair.doi...........688f5b6ae94538112b11debc8feeb626
Full Text :
https://doi.org/10.1023/a:1021380311747