Highly Stable Optically Induced Birefringence and Holographic Surface Gratings on a New Azocarbazole-Based Polyimide

An azocarbazole-based polyimide was synthesized from an azocarbazole diamine monomer and 4,4‘-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) by a two-step polycondensation reaction. Birefringence experiments have been performed on the pure polyimide and on the polyimide mixed with small azo chromophores. Because of its high Tg, the polyimide has a very stable induced birefringence (only 14% loss during the relaxation process). The stability of the mixtures is also very high. Surface relief diffraction gratings were inscribed on these systems. The measured diffraction efficiency was about 0.25% for a diamine-doped polyimide exposed for 1 h to an irradiance of 200 mW/cm2. The surface profile studied by atomic force microscopy showed an amplitude of 30 nm and a regular spacing of 700 nm on a 255 nm thick film. The photoinduced gratings had a high stability without further surface deformation after baking at 240 °C for 1 h in air.