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Densities, Speeds of Sound, Excess Molar Volumes, and Excess Isentropic Compressibilities at T = (298.15 and 308.15) K for Methyl Methacrylate + 1-Alkanols (1-Butanol, 1-Pentanol, and 1-Heptanol) + Cyclohexane, + Benzene, + Toluene, + p-Xylene, and + Ethylbenzene

Authors :
Saurabh S. Soni
Sunil R. Patel
Nandhibatla V. Sastry
Source :
Journal of Chemical & Engineering Data. 56:142-152
Publication Year :
2010
Publisher :
American Chemical Society (ACS), 2010.

Abstract

The densities and speeds of sound for ternary mixtures of methyl methacrylate (MMA) + 1-alkanols (1-butanol, 1-pentanol, 1-heptanol) + aromatic organic solvents (benzene, toluene, p-xylene, and ethylbenzene) or + cyclohexane have been measured at T/K = (298.15 and 308.15). Excess molar volumes and excess isentropic compressibilities were calculated across the mole fraction range, and the same were compared with the values calculated using similar data for the binary pairs through Redlich−Kister (RK), Tsao and Smith (TS), and Kohler (K) equations. As compared to others, the RK equation predicted the excess molar volumes and excess isentropic compressibilities adequately.

Details

ISSN :
15205134 and 00219568
Volume :
56
Database :
OpenAIRE
Journal :
Journal of Chemical & Engineering Data
Accession number :
edsair.doi...........6a9cd2575506cfa0abb7748bb9348f8b
Full Text :
https://doi.org/10.1021/je100652b