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Synthesis, spectral luminescent properties, and photostability of monoiodo- and dibromo-substituted BF2-dipyrrinates

Authors :
Anatoly I. Vyugin
Rimma T Kuznetsova
Mikhail B. Berezin
Elena V. Antina
Galina B. Guseva
E. N. Nuraneeva
Source :
Russian Journal of General Chemistry. 86:840-847
Publication Year :
2016
Publisher :
Pleiades Publishing Ltd, 2016.

Abstract

4-Iodo-, 4,4′-, and 5,5′-dibromo-substituted BF2-dipyrrinates (BODIPY) have been prepared, and their spectral luminescent properties and photostability have been studied. It has been shown that the introduction of iodine and bromine atoms in the molecule structure results in build-up of the BODIPY phosphorescence and decrease in their fluorescence quantum yield. Basing on the obtained data, the prepared dipyrrinates can be recommended for development of fluorescent sensors for medical and technical applications.

Details

ISSN :
16083350 and 10703632
Volume :
86
Database :
OpenAIRE
Journal :
Russian Journal of General Chemistry
Accession number :
edsair.doi...........6c2e2819568a86d2dc533c45972f8e10
Full Text :
https://doi.org/10.1134/s1070363216040149