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Hydrotalcite-supported Pd–Au nanocatalysts for Ullmann homocoupling reactions at low temperature
- Source :
- New J. Chem.. 41:1905-1908
- Publication Year :
- 2017
- Publisher :
- Royal Society of Chemistry (RSC), 2017.
-
Abstract
- Hydrotalcite-supported Pd–Au nanocatalysts were found to be efficient heterogeneous catalysts for Ullmann homocoupling reactions of aryl bromides or chlorides at 25 or 40 °C, which could be due to the ensemble effect and increased electron density of Pd sites on Pd–Au nanoparticles, and the assistant role of the hydrotalcite for the reversion of the catalytic active center, Pd(0).
- Subjects :
- Hydrotalcite
010405 organic chemistry
Aryl
Nanoparticle
Nanotechnology
General Chemistry
010402 general chemistry
01 natural sciences
Catalysis
Nanomaterial-based catalyst
0104 chemical sciences
Ensemble effect
Active center
chemistry.chemical_compound
chemistry
Polymer chemistry
Materials Chemistry
Subjects
Details
- ISSN :
- 13699261 and 11440546
- Volume :
- 41
- Database :
- OpenAIRE
- Journal :
- New J. Chem.
- Accession number :
- edsair.doi...........6c6c4f80b128030f7a17ac8f007125fc