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ChemInform Abstract: Gold(I)-Catalyzed Reactions of 1-(ortho-Alkynylaryl)ureas: Highly Selective Heterocyclization and Synthesis of Mixed N,O-Acetals

Authors :
Gregorio Asensio
Mercedes Medio-Simón
Ana Gimeno
Ana B. Cuenca
Source :
ChemInform. 45
Publication Year :
2014
Publisher :
Wiley, 2014.

Abstract

Treatment of alkynylureas (I) with trifluoroethanol in the presence of a Au/Ag catalytic system provides N-6-exo-dig heterocyclization products (III) and in some cases open chain acetals as side products.

Details

ISSN :
09317597
Volume :
45
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........6ca1985ceff265b3666c19e130519688
Full Text :
https://doi.org/10.1002/chin.201431173