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Fluorine-planted titanosilicate with enhanced catalytic activity in alkene epoxidation with hydrogen peroxide

Authors :
Haihong Wu
Qiang Wang
Yueming Liu
Anmin Zheng
Xiangqing Fang
Feng Deng
Xiujuan Deng
Yuning Wang
Mingyuan He
Peng Wu
Source :
Catalysis Science & Technology. 2:2433
Publication Year :
2012
Publisher :
Royal Society of Chemistry (RSC), 2012.

Abstract

Fluorine species were successfully implanted into a MWW-type titanosilicate via post-treatment, which generates the SiO3/2F units in the zeolite framework. The incorporated fluorine species significantly improved the catalytic performance in the epoxidation of alkenes as a result of enhancing the Lewis acid strength and the hydrophobicity of the zeolite.

Details

ISSN :
20444761 and 20444753
Volume :
2
Database :
OpenAIRE
Journal :
Catalysis Science & Technology
Accession number :
edsair.doi...........6d09cb436043f924702299d5eccb022b
Full Text :
https://doi.org/10.1039/c2cy20446k