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A novel pyrrolidinium ionic liquid with 1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoroethoxy)ethanesulfonate anion as a recyclable reaction medium and efficient catalyst for Friedel–Crafts alkylations of indoles with nitroalkenes
- Source :
- Journal of Fluorine Chemistry. 130:394-398
- Publication Year :
- 2009
- Publisher :
- Elsevier BV, 2009.
-
Abstract
- A series of pyrrolidinium-based salts with new fluorine-containing anions were synthesized. Different melting points could be obtained by changing the length of the fluoroalkyl chain of the anions. The pyrrolidinium 1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoroethoxy)ethanesulfonate ([C 4 H 8 NH 2 ][H(CF 2 ) 4 O(CF 2 ) 2 SO 3 ]) is highly fluid even below room temperature. It can be used both as a recyclable solvent and as an efficient catalyst for Friedel–Crafts alkylations of indoles with nitroalkenes.
- Subjects :
- Organic Chemistry
chemistry.chemical_element
Biochemistry
Ion
Inorganic Chemistry
Solvent
chemistry.chemical_compound
chemistry
Polymer chemistry
Ionic liquid
Fluorine
Melting point
Environmental Chemistry
Organic chemistry
Physical and Theoretical Chemistry
Efficient catalyst
Friedel–Crafts reaction
Subjects
Details
- ISSN :
- 00221139
- Volume :
- 130
- Database :
- OpenAIRE
- Journal :
- Journal of Fluorine Chemistry
- Accession number :
- edsair.doi...........6f13c44439abaa191f553c2b5d45f27f