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Improvement of the electrochemical properties of 'as-grown' boron-doped polycrystalline diamond electrodes deposited on tungsten wires using ethanol

Authors :
Alfredo C. Peterlevitz
Flavio Santos Damos
Helder José Ceragioli
Vitor Baranauskas
Reinaldo F. Teófilo
Lauro T. Kubota
Leonardo M. Da Silva
Márcia M. C. Ferreira
Source :
Journal of Solid State Electrochemistry. 11:1449-1457
Publication Year :
2007
Publisher :
Springer Science and Business Media LLC, 2007.

Abstract

The electrochemical properties of boron-doped diamond (BDD) polycrystalline films grown on tungsten wire substrates using ethanol as a precursor are described. The results obtained show that the use of ethanol improves the electrochemistry properties of "as-grown" BDD, as it minimizes the graphitic phase upon the surface of BDD, during the growth process. The BDD electrodes were characterized by Raman spectroscopy, scanning electronic microscopy, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The boron-doping levels of the films were estimated to be ∼10 20 B/cm 3 . The electro- chemical behavior was evaluated using the Fe CN

Details

ISSN :
14330768 and 14328488
Volume :
11
Database :
OpenAIRE
Journal :
Journal of Solid State Electrochemistry
Accession number :
edsair.doi...........6f892a4e73110c3218a93aa6c6c57d68
Full Text :
https://doi.org/10.1007/s10008-007-0319-z