Preparation of Ti(C, N)-based Cermets Powders with Double-core Ring Structure

In this study, the microstructure of Ti(C, N)-based cermet was improved by adding β-cobalt (face-centered cubic) and (Ti, W, Mo, Ta)(C, N) solid solution powder to prepare micro-nano Ti(C, N)-based cermet powder. In order to improve the comprehensive properties of the material. Firstly, the Co powder with face-centered cubic structure was obtained by the solid-phase reaction of high-energy ball milling, and its plastic deformation resistance was higher than that of Co powder with dense hexagonal structure. Secondly, The powder of (Ti, W, Mo, Ta)(C, N)solid solution was obtained by mechanical alloying and high-temperature carbonization under the atmosphere of N2. And the two were applied to the micro-nano Ti(C, N)-based cermet powder, and finally the properties of cermet powder were compared with that of ordinary cermet powder. The results show that the microstructure of micro-Ti(C, N)-based cermet powder prepared in this study is a double-core rim structure, that is, the structure of black core white rim and gray core white rim. This structure can effectively prevent crack of the expansion. The strength and toughness of cermet materials are greatly improved, which is beneficial to the improvement of comprehensive properties of cermet materials.