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Observation of discrete thiazolidine ring conformations in frozen aqueous solutions of penicillins by13C CP–MAS NMR spectroscopy

Authors :
Jamila Fattah
J. Mark Twyman
Christopher M. Dobson
Source :
J. Chem. Soc., Chem. Commun.. :647-649
Publication Year :
1991
Publisher :
Royal Society of Chemistry (RSC), 1991.

Abstract

Resonances from two distinct thiazolidine ring conformers have been resolved in the 13C CP-MAS spectra of frozen aqueous solutions of penicillins; the relative intensities of the resonances correlate well with previous estimates of the populations of the different conformers in liquid aqueous solutions.

Details

ISSN :
00224936
Database :
OpenAIRE
Journal :
J. Chem. Soc., Chem. Commun.
Accession number :
edsair.doi...........706cc2b966ca2393366949cccc097dba
Full Text :
https://doi.org/10.1039/c39910000647