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Highly Diastereoselective Synthesis of Chiral Furans with a Quaternary Carbon Substituent at the 2-Position Using 8-Phenylmenthol as the Chiral Auxiliary

Authors :
Akihisa Iwamoto
Aki Katori
Satoshi Kojima
Yohsuke Yamamoto
Yoshiaki Sashihara
Source :
Chemistry Letters. 43:766-768
Publication Year :
2014
Publisher :
The Chemical Society of Japan, 2014.

Abstract

The reaction of cis-4-oxo-2-pentenal and 8-phenylmenthyl 2-oxocyclopentane-1-carboxylate in the presence of a fluorinated cosolvent afforded the corresponding furan product with a high diastereosel...

Details

ISSN :
13480715 and 03667022
Volume :
43
Database :
OpenAIRE
Journal :
Chemistry Letters
Accession number :
edsair.doi...........70aed36e1c8b387cc67a1b681a925993
Full Text :
https://doi.org/10.1246/cl.140052