DIPPR Project 851 – Thirty Years of Vapor–Liquid Critical Point Measurements and Experimental Technique Development

Experimentally determined critical temperatures (Tc) and critical pressures (Pc) are reported for 64 compounds. In addition, the critical volume (Vc) has been experimentally determined for 14 of these compounds. The compounds in this study are of industrial interest in process design, simulation, and safety. These data also extend our understanding of and ability to predict these properties from group contribution methods.