Back to Search
Start Over
ChemInform Abstract: Selective Synthesis of o-Acylbenzylphosphonates by Insertion Reactions of Arynes into β-Ketophosphonates
- Source :
- ChemInform. 41
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- A mild method for selective synthesis of o-acylbenzylphosphonates has been developed by the reactions of arynes with β-ketophosphonates. In the presence of CsF and THF, the carbon−carbon σ-bonds of 2-oxopropylphosphonates were selectively cleaved and added to arynes providing the corresponding 2-acylbenzylphosphonates in moderate to good yields.
- Subjects :
- Chemistry
General Medicine
Aryne
Combinatorial chemistry
Subjects
Details
- ISSN :
- 15222667 and 09317597
- Volume :
- 41
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........70cd4b5f70b100ee7f200c30ef3beaa3