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Standard Gibbs energies of transfer of potassium tetraphenylborate from water to straight-chain n-alkanols
- Source :
- Journal of Solution Chemistry. 24:499-509
- Publication Year :
- 1995
- Publisher :
- Springer Science and Business Media LLC, 1995.
-
Abstract
- Solubilities of potassium tetraphenylborate in water, methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-octanol at 15, 25, 35, 45, 55°C have been determined by spectrophotometry. The standard Gibbs energy of transfer of potassium tetraphenylborate form water to straightchain n-alkanols and the medium effect of potassium tetraphenylborate from 15 to 55°C have been calculated. Furthermore, the contribution of microscopic interactions to the standard Gibbs energy of transfer of potassium tetraphenylborate is calculated and discussed.
- Subjects :
- Activity coefficient
Aqueous solution
medicine.diagnostic_test
Inorganic chemistry
Biophysics
Solvation
Biochemistry
Gibbs free energy
chemistry.chemical_compound
symbols.namesake
chemistry
Mass transfer
Spectrophotometry
medicine
symbols
Methanol
Physical and Theoretical Chemistry
Molecular Biology
Potassium tetraphenylborate
Subjects
Details
- ISSN :
- 15728927 and 00959782
- Volume :
- 24
- Database :
- OpenAIRE
- Journal :
- Journal of Solution Chemistry
- Accession number :
- edsair.doi...........7438c12b328ff9beb5e63cf8bcb7e64e