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Standard Gibbs energies of transfer of potassium tetraphenylborate from water to straight-chain n-alkanols

Authors :
Song-Sheng Qu
Lizhuang Zou
Xiao-ling Wang
Lin-Wei Li
Da-Cheng Li
Baoxue Zhou
Source :
Journal of Solution Chemistry. 24:499-509
Publication Year :
1995
Publisher :
Springer Science and Business Media LLC, 1995.

Abstract

Solubilities of potassium tetraphenylborate in water, methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-octanol at 15, 25, 35, 45, 55°C have been determined by spectrophotometry. The standard Gibbs energy of transfer of potassium tetraphenylborate form water to straightchain n-alkanols and the medium effect of potassium tetraphenylborate from 15 to 55°C have been calculated. Furthermore, the contribution of microscopic interactions to the standard Gibbs energy of transfer of potassium tetraphenylborate is calculated and discussed.

Details

ISSN :
15728927 and 00959782
Volume :
24
Database :
OpenAIRE
Journal :
Journal of Solution Chemistry
Accession number :
edsair.doi...........7438c12b328ff9beb5e63cf8bcb7e64e