ChemInform Abstract: Synthesis of Acylphosphonates by a Palladium-Catalyzed Phosphonocarbonylation Reaction of Aryl Iodides with Phosphites

Authors :: Yusuke Masuda
Masahiro Murakami
Naoki Ishida
Source :: ChemInform. 46
Publication Year :: 2015
Publisher :: Wiley, 2015.
Abstract: Acylphosphonates are conveniently synthesized from aryl iodides by a palladium-catalyzed reaction with dialkyl phosphites under an atmospheric pressure of carbon monoxide. The reaction demonstrates the first example of the use of phosphorus nucleophiles in related metal-catalyzed carbonylation reactions.

Subjects :: chemistry.chemical_compound
Nucleophile
chemistry
Atmospheric pressure
Aryl
Phosphorus
Organic chemistry
chemistry.chemical_element
General Medicine
Carbonylation
Catalysis
Carbon monoxide
Palladium

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