Convenient synthesis of Pt(0) olefin complexes by colorimetric reduction of Pt(II) complexes with SmI2

Authors :: Hideo Kurosawa
Sensuke Ogoshi
Masaki Morita
Katsuharu Inoue
Source :: Journal of Organometallic Chemistry. 689:662-665
Publication Year :: 2004
Publisher :: Elsevier BV, 2004.
Abstract: Homoleptic olefin platinum(0) complexes, Pt(C 7 H 10 ) 3 and Pt(cod) 2 , were synthesized by the colorimetric reduction of platinum(II) complexes with SmI 2 in the presence of 2-norbornene or COD. This is a practically more convenient method for the synthesis of the Pt(0) complexes than the literature method employing Li 2 (cot).

Subjects :: Inorganic Chemistry
Reduction (complexity)
Olefin fiber
chemistry.chemical_compound
chemistry
Organic Chemistry
Inorganic chemistry
Materials Chemistry
chemistry.chemical_element
Physical and Theoretical Chemistry
Homoleptic
Platinum
Biochemistry

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