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Ferrocenyltriazoles from 3β,28-Diacylbetulin: Synthesis and Cytotoxic Activity

Authors :
D. V. Eroshenko
D. A. Shemyakina
A. R. Galeev
I. G. Mokrushin
Maksim V. Dmitriev
L. V. Pavlogradskaya
Vladimir A. Glushkov
N. K. Zhukova
Source :
Russian Journal of Organic Chemistry. 55:1690-1697
Publication Year :
2019
Publisher :
Pleiades Publishing Ltd, 2019.

Abstract

The reaction of 30-bromo-3β,28-diacylbetulin with sodium azide afforded 30-azido-3β,28-diacyloxylup-20(29)-enes. The products were subjected to a CuI/TMEDA-catalyzed click reaction with ethynylferrocene to obtain the corresponding ferrocene-betulin conjugates with a 1,2,3-triazole linker.

Details

ISSN :
16083393 and 10704280
Volume :
55
Database :
OpenAIRE
Journal :
Russian Journal of Organic Chemistry
Accession number :
edsair.doi...........768baf47a89691182c05542031f22146
Full Text :
https://doi.org/10.1134/s1070428019110083