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Predicting and creating 7-connected Zn4O vertices for the construction of an exceptional metal–organic framework with nanoscale cages

Authors :
Zhenxia Chen
Mingli Deng
Bai Shizhe
Feilong Yang
Linhong Weng
Weiquan Zhang
Yun Ling
Yaming Zhou
Source :
CrystEngComm. 17:1923-1926
Publication Year :
2015
Publisher :
Royal Society of Chemistry (RSC), 2015.

Abstract

A 7-connected Zn4O unit has been theoretically predicted based on basic zinc acetate [Zn4O(CH3COO)6], which was then experimentally extended into a three-dimensional structure featuring three kinds of nanocage in a unit cell.

Details

ISSN :
14668033
Volume :
17
Database :
OpenAIRE
Journal :
CrystEngComm
Accession number :
edsair.doi...........77631a68eb2f130d16d55f8ad6842fb5
Full Text :
https://doi.org/10.1039/c4ce02415j