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Synthesis of BiOBr x I 1−x solid solutions with dominant exposed {0 0 1} and {1 1 0} facets and their visible-light-induced photocatalytic properties
- Source :
- Separation and Purification Technology. 203:75-83
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- The BiOBrxI1−x solid solutions were successfully synthesized both in water and ethylene glycol (EG), using a facile solvothermal method. The as-prepared BiOBrxI1−x solid solutions were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), UV–vis spectrometer and so on. SEM images revealed that BiOBrxI1−x solid solutions formed 2D plate-like shape in water, and formed microspheres in EG solvent; except that BiOI formed nanoparticles in EG solvent. The photocatalytic performance of all the BiOBrxI1-x solid solutions samples were investigated by degrading phenol under visible light irradiation (λ > 420 nm). The BiOBr0.5I0.5 microspheres with highly exposed {1 1 0} facets showed the highest photocatalytic activity with phenol completely degraded within 80 min under visible light irradiation. In addition, a reasonable mechanism for the enhanced photocatalytic performance was also discussed in detail.
- Subjects :
- Materials science
Scanning electron microscope
Nanoparticle
Filtration and Separation
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
Analytical Chemistry
Solvent
chemistry.chemical_compound
chemistry
Photocatalysis
Phenol
0210 nano-technology
Ethylene glycol
Nuclear chemistry
Solid solution
Visible spectrum
Subjects
Details
- ISSN :
- 13835866
- Volume :
- 203
- Database :
- OpenAIRE
- Journal :
- Separation and Purification Technology
- Accession number :
- edsair.doi...........77ecc62e2541252b55a2cfb478c904e3