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Electronic Structure of Ligand-Bridged Complexes Containing the [Rh2]3+ Core: ESR Spectroscopy, MO Calculations, and X-ray Structures of the Three Redox Pairs [Rh2(CO)2LL'{.mu.-PhNC(Me)NPh}2]z [z = 0, 1; L = L' = PPh3, P(OPh)3; L = PPh3, L' = P(OPh)3]
- Source :
- Inorganic Chemistry. 33:960-971
- Publication Year :
- 1994
- Publisher :
- American Chemical Society (ACS), 1994.
-
Abstract
- The X-ray crystal structure analyses of the three redox pairs [Rh 2 (CO) 2 LL'{μ-PhNC(Me)NPh)} 2 ] z [z=0,1; L=L'=PPh 3 (1, 1 + ); L=L'=P(OPh) 3 (1, 1 + ); L=PPh 3 , L'= P(OPh) 3 (3, 3 + )] are reported and the molecular structures compared with those of [Rh 2 (CO) 2 (PPh 3 ) 2 (μ-RNNNR) 2 ] z [z=0,1; R=p-tolyl (4, 4 + )]
Details
- ISSN :
- 1520510X and 00201669
- Volume :
- 33
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry
- Accession number :
- edsair.doi...........78c1b0aa2a1d0c024e64e6ce6694eb9b
- Full Text :
- https://doi.org/10.1021/ic00083a021