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Electronic Structure of Ligand-Bridged Complexes Containing the [Rh2]3+ Core: ESR Spectroscopy, MO Calculations, and X-ray Structures of the Three Redox Pairs [Rh2(CO)2LL'{.mu.-PhNC(Me)NPh}2]z [z = 0, 1; L = L' = PPh3, P(OPh)3; L = PPh3, L' = P(OPh)3]

Authors :
Carlo Mealli
Karen E. Richardson
Kent R. Mann
Gabriel Garcia Herbosa
A. Guy Orpen
Philip H. Rieger
David C. Boyd
Michael G. Hill
Neil G. Connelly
Source :
Inorganic Chemistry. 33:960-971
Publication Year :
1994
Publisher :
American Chemical Society (ACS), 1994.

Abstract

The X-ray crystal structure analyses of the three redox pairs [Rh 2 (CO) 2 LL'{μ-PhNC(Me)NPh)} 2 ] z [z=0,1; L=L'=PPh 3 (1, 1 + ); L=L'=P(OPh) 3 (1, 1 + ); L=PPh 3 , L'= P(OPh) 3 (3, 3 + )] are reported and the molecular structures compared with those of [Rh 2 (CO) 2 (PPh 3 ) 2 (μ-RNNNR) 2 ] z [z=0,1; R=p-tolyl (4, 4 + )]

Details

ISSN :
1520510X and 00201669
Volume :
33
Database :
OpenAIRE
Journal :
Inorganic Chemistry
Accession number :
edsair.doi...........78c1b0aa2a1d0c024e64e6ce6694eb9b
Full Text :
https://doi.org/10.1021/ic00083a021