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A Chiral Director Field in the Nematic Liquid Crystal Phase Induced by a Poly(.gamma.-benzyl glutamate) Chemical Reaction Alignment Film
- Source :
- Langmuir. 11:4838-4843
- Publication Year :
- 1995
- Publisher :
- American Chemical Society (ACS), 1995.
-
Abstract
- Poly(y-benzyl glutamate) (PBG) bonded covalently to a flat substrate at a terminal position of the main chain and formed an aligned dipole layer because of its rigidity. The authors call this a poly(y-benzyl glutamate) chemical reaction alignment (PBG-CRA) film. Using the PBG-CRA film as an orienting film for nematic liquid crystals, liquid crystal molecules were oriented spirally to generate a novel chiral director field in the liquid crystal phase despite the absence of chirality in the liquid crystal molecule, the sense of which depended on that of the α-helical structure of PBG on the surface, resulting in the observation of a spiral texture. Since the liquid crystal molecules in the vicinity of the PBG-CRA film were able to respond more rapidly to an applied electric field than those for a rubbed polyimide film and werq responsive at voltage frequencies in the MHz region, we conclude from our investigations by time-resolved infrared spectroscopy that the PBG molecules are reversibly responsive to an external stimulation due to their rigidity and large dipole moments and that the dipole-dipole interaction takes place between the PBG molecules and the interfacial liquid crystal molecules.
- Subjects :
- Stereochemistry
Chemistry
Physics::Optics
Infrared spectroscopy
Surfaces and Interfaces
Crystal structure
Condensed Matter Physics
Dipole
Crystallography
Liquid crystal
Condensed Matter::Superconductivity
Monolayer
Electrochemistry
Molecule
General Materials Science
Surface charge
Chirality (chemistry)
Spectroscopy
Subjects
Details
- ISSN :
- 15205827 and 07437463
- Volume :
- 11
- Database :
- OpenAIRE
- Journal :
- Langmuir
- Accession number :
- edsair.doi...........796cbd8d2a285a39117ec4265d5522bd