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Edge-carboxylated graphene nanoplatelets as efficient electrode materials for electrochemical supercapacitors
- Source :
- Carbon. 142:89-98
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- Edge-carboxylated graphene nanoplatelets (ECG), prepared by a mechano-chemical reaction (or ball milling method) in the presence of dry ice, are eligible for an efficient electrode materials for electrochemical supercapacitors. ECG contained a higher content of edge-carboxylic groups with less structural defects, compared with the nitrogen-doped carboxylic graphene (NGOOH) prepared from the conventional solution-exfoliation of graphite. The structural defects level of ECG is ca. 16.2%, while it was ca. 48.9% for NGOOH. The edge-carboxylation increases the electroactive surface area, hydrophilicity and wettability of graphene without serious deterioration of the intrinsic properties e.g., chemical, mechanical and electronic properties. In result, it is more effective in enabling ion adsorption and rapid electrolyte diffusion within the pores of graphene which results in a significant increase of specific capacitance (Csp) to 365.72 F/g at a current density of 1 A/g, with a good charge–discharge property and rate capability for ECG. On the other hand, the Csp significantly decreases to ca. 175.05 F/g for NGOOH, as its high level of structural defects seriously affected its electronic properties.
- Subjects :
- Materials science
Graphene
Diffusion
02 engineering and technology
General Chemistry
Electrolyte
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Capacitance
0104 chemical sciences
law.invention
Chemical engineering
law
General Materials Science
Graphite
Wetting
0210 nano-technology
Ball mill
Current density
Subjects
Details
- ISSN :
- 00086223
- Volume :
- 142
- Database :
- OpenAIRE
- Journal :
- Carbon
- Accession number :
- edsair.doi...........7997840077a5076791af9bc91d6339f2