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Facile synthesis of γ-alkylidenebutenolides from Morita–Baylis–Hillman adducts

Authors :
Jin Woo Lim
Ko Hoon Kim
Bo Ram Park
Jae Nyoung Kim
Source :
Tetrahedron Letters. 53:36-40
Publication Year :
2012
Publisher :
Elsevier BV, 2012.

Abstract

An expedient synthetic procedure of γ-alkylidenebutenolides was developed via a sequential indium-mediated Barbier-type reaction of Morita–Baylis–Hillman bromide with aldehyde, lactonization, and double-bond isomerization. Various γ-alkylidenebutenolides including bovolide and its derivatives were synthesized in good overall yields.

Details

ISSN :
00404039
Volume :
53
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........7b50af6dccbf781fdbdf51ad260faf48
Full Text :
https://doi.org/10.1016/j.tetlet.2011.11.001