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A facile synthesis of 3-trifluoromethyl-1,2,4-oxadiazoles from cyanamides

Authors :
James S. Scott
David S. Clarke
Kristin Goldberg
Source :
Tetrahedron Letters. 55:4433-4436
Publication Year :
2014
Publisher :
Elsevier BV, 2014.

Abstract

A safe and facile method for the formation of 3-trifluoromethyl-5-amino-1,2,4-oxadiazoles, via a reversed addition of hydroxylamine to cyanamides, is reported. This two-pot procedure is suitable to scale-up and avoids the hazards associated with trifluoromethyl amidoxime synthesis.

Details

ISSN :
00404039
Volume :
55
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........7b7c0683b0c0ec619176d31bd25c2c5a
Full Text :
https://doi.org/10.1016/j.tetlet.2014.06.019