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catena-Poly[[bis(α-thenoyltrifluoroacetonato)copper(II)]-μ-1,4-di-4-pyridyl-2,3-diazabuta-1,3-diene]

Authors :
Tamara Maxwell
Andrea M. Goforth
Hans-Conrad zur Loye
William J. Perkins
Mark D. Smith
LeRoy Peterson
Source :
Acta Crystallographica Section E Structure Reports Online. 61:m2047-m2049
Publication Year :
2005
Publisher :
International Union of Crystallography (IUCr), 2005.

Abstract

In the one-dimensional title polymer, [Cu(C8H4F3O2S)2(C12H10N4)]n or [Cu(L)2(tta)2] [tta is α-thenoyl­trifluoro­acetonato and L is 1,4-bis­(4-pyrid­yl)-2,3-diaza-1,3-butadiene], Cu2+ lies on a center of inversion. It is axially coordinated by two pyridyl N atoms from two different L ligands and equatorially coordinated by four O atoms from two chelating tta ligands. The ligand L propagates the one-dimensional chain structure by serving as a bridging ligand between two Cu octa­hedra via Cu—N coordinate bonds.

Details

ISSN :
16005368
Volume :
61
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........7cddc820e0746a15c37489b9f15de3b2
Full Text :
https://doi.org/10.1107/s1600536805028631