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Thermally Reversible Cross-linkers To Facilitate the Improved Reprocessability of Poly(butyl methanol methacrylate) Rubber with Excellent Thermal and Mechanical Properties
- Source :
- Industrial & Engineering Chemistry Research. 57:946-953
- Publication Year :
- 2018
- Publisher :
- American Chemical Society (ACS), 2018.
-
Abstract
- This work takes advantage of the unique thermally reversible dissociation/association feature of C–ON bonds in alkoxyamine (Diol) to facilitate the reprocessability of poly(butyl methanol methacrylate) (PBMM) rubber with excellent thermal and mechanical properties. Isocyanate groups were incorporated into the PBMM backbone and then reacted with hydroxyl groups in Diol to obtain cross-linked PBMM rubber. Although its cross-linking degree is slightly lower than the conventional cross-linked rubber by an irreversible cross-linker (Dieg), it shows a higher tensile strength and elongation at break. Its decomposition temperature is about 50 °C higher than PBMM cross-linked by Dieg. Furthermore, the dissociation of C–ON bond at high temperature can break the cross-linking network of PBMM rubber to form a flowable and reprocessable melt and show an excellent ability of reshaping and healing; the association of thermally reversible C–ON bond can completely recover the cross-linking network and mechanical propertie...
- Subjects :
- Materials science
General Chemical Engineering
Diol
Thermal decomposition
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
Methacrylate
01 natural sciences
Isocyanate
Industrial and Manufacturing Engineering
Dissociation (chemistry)
0104 chemical sciences
chemistry.chemical_compound
chemistry
Chemical engineering
Natural rubber
visual_art
Ultimate tensile strength
visual_art.visual_art_medium
Methanol
0210 nano-technology
Subjects
Details
- ISSN :
- 15205045 and 08885885
- Volume :
- 57
- Database :
- OpenAIRE
- Journal :
- Industrial & Engineering Chemistry Research
- Accession number :
- edsair.doi...........7df739ac9a65f84c1e39d16f7ee78df6