Bis(2,6-difluorophenyl)benzoylmethyl cation: α-ketocarbenium ion as a single-electron acceptor

Authors :: Toshikazu Kitagawa
Makoto Nishimura
Kunio Okamoto
Kenítichi Takeuchi
Source :: Tetrahedron Letters. 32:3187-3190
Publication Year :: 1991
Publisher :: Elsevier BV, 1991.
Abstract: The title carbenium ion 1 was observed by low temperature NMR in solution. Its strong oxidizing power was demonstrated by the reduction potential and the effective oxidation of methoxy-substituted benzopinacolone 3 .

Subjects :: chemistry.chemical_classification
Reaction mechanism
Ketone
Chemistry
Organic Chemistry
Free-radical reaction
Nuclear magnetic resonance spectroscopy
Photochemistry
Biochemistry
Acceptor
Ion
Carbenium ion
chemistry.chemical_compound
Drug Discovery
Oxidizing agent
Organic chemistry

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