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ChemInform Abstract: Direct Synthesis of B-Allyl and B-Allenyldiisopinocampheylborane Reagents Using Allyl or Propargyl Halides and Indium Metal under Barbier-Type Conditions

Authors :
Lacie C. Hirayama
Terra D. Haddad
Bakthan Singaram
Allen G. Oliver
Source :
ChemInform. 43
Publication Year :
2012
Publisher :
Wiley, 2012.

Abstract

The intermediate borane reagents react with carbonyl compounds to afford homoallylic and homopropargylic alcohols with low to excellent enantioselectivity.

Details

ISSN :
09317597
Volume :
43
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........7e2ad8d82e22d172fd90ff736af6d5e7
Full Text :
https://doi.org/10.1002/chin.201234162