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MOF-derived CuCoNi trimetallic hybrids as efficient oxygen evolution reaction electrocatalysts

Authors :
Fanbao Meng
Yu Fu
Boyan Lu
Tieqiang Wang
Junchao Ma
Yunong Li
Wenxiu He
Sha Wang
Xiaojue Bai
Junyi Chen
Liying Zhang
Xuemin Zhang
Source :
New Journal of Chemistry. 44:2459-2464
Publication Year :
2020
Publisher :
Royal Society of Chemistry (RSC), 2020.

Abstract

Metal–organic frameworks (MOFs) as templates can easily form homogeneous multimetallic materials via metal ion exchange, and they have been widely used as electrocatalysts in the oxygen evolution reaction (OER) due to the synergistic effect of the metal ions. Herein, by selecting Cu(BDC) as a template, a simple one-step impregnation method was used to prepare CuCoNi trimetallic electrocatalysts, which exhibited excellent catalytic performance for the OER with a low overpotential of 327 mV at a 10 mA cm−2 current density and a small Tafel slope of 75.7 mV dec−1. The outstanding OER activity may be attributed to the transformed 2D lamellar morphology, amorphous structure and the synergistic effect of the metal species.

Details

ISSN :
13699261 and 11440546
Volume :
44
Database :
OpenAIRE
Journal :
New Journal of Chemistry
Accession number :
edsair.doi...........7ecb4ebcc15711158c0786025896de03
Full Text :
https://doi.org/10.1039/c9nj05562b