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Efficient fixation of CO2 at mild conditions by a Cr-conjugated microporous polymer
- Source :
- Journal of Energy Chemistry. 23:22-28
- Publication Year :
- 2014
- Publisher :
- Elsevier BV, 2014.
-
Abstract
- We reported a bifunctional material, Cr-salen implanted conjugated microporous polymer (Cr-CMP), which is able to capture excellent CO2 amounts and has a remarkable catalytic activity towards the cycloaddition reaction of CO2 to epoxides forming cyclic carbonates at mild conditions without additional solvents. This heterogeneous Cr-CMP catalyst has a superior catalytic activity to its related homogeneous catalyst and can be reused more than ten times without a significant decrease in catalytic activity.
- Subjects :
- chemistry.chemical_classification
Energy Engineering and Power Technology
Homogeneous catalysis
Polymer
Cycloaddition
Catalysis
Conjugated microporous polymer
chemistry.chemical_compound
Fuel Technology
chemistry
Polymer chemistry
Electrochemistry
Organic chemistry
Bifunctional
Energy (miscellaneous)
Subjects
Details
- ISSN :
- 20954956
- Volume :
- 23
- Database :
- OpenAIRE
- Journal :
- Journal of Energy Chemistry
- Accession number :
- edsair.doi...........7f0805a8c624ec35e1ea2cda6d7d6767