Back to Search Start Over

Asymmetric double aldol reaction of chiral acetyloxazolidinone

Authors :
Hiroshi Furuno
Atsushi Abiko
Tadashi Inoue
Source :
Tetrahedron Letters. 43:8297-8299
Publication Year :
2002
Publisher :
Elsevier BV, 2002.

Abstract

Treatment of chiral oxazolidinone with Bu 2 BOTf (2.5 equiv.) and Et 3 N (3.0 equiv.) quantitatively produced the doubly borylated enolate, which afforded the double aldol products with high diastereoselectivity after reaction with aldehydes.

Details

ISSN :
00404039
Volume :
43
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........803a6a657ea7cfa34185a8692419820e
Full Text :
https://doi.org/10.1016/s0040-4039(02)02021-x