Isopropyl alcohol: an unusual, powerful, ‘green’ solvent for the preparation of silicone–urea copolymers with high urea contents

Isopropyl alcohol (IPA) is used as the reaction solvent for the preparation of silicone–urea copolymers. Reactivity of isopropanol with bis(4-isocyanatocyclohexyl)methane (HMDI) was investigated at 23 °C using infrared spectroscopy. Spectroscopic studies indicated very low reactivity of IPA towards HMDI at 23 °C. High molecular weight segmented silicone–urea copolymers were prepared through the reaction of HMDI with aminopropyl and N-methylaminopropyl terminated polydimethylsiloxane (PDMS) oligomers and three different chain extenders, ethylene diamine (ED), hexamethylene diamine (HMDA) and 2-methyl-1,5-diaminopentane (Dytek A). Number average molecular weights of PDMS oligomers varied between 900 and 7000 g/mol, respectively. Reactions were carried out at room temperature in IPA. Silicone–urea copolymers with urea hard segment content between 10 and 42% by weight were prepared. Thermal and mechanical characterization of the copolymers indicated the formation of microphase-separated systems with excellent tensile strengths. Interestingly, structure of the diamine chain extender did not show any influence on the mechanical properties of the homologous series of silicone–urea copolymers.