Reductive Elimination ofsym-Diphenyltetramethyldisilane fromcis-Bis(pheny1dimethylsilyl)bis(phosphine)platinum(II) Complexes

Authors :: Kobayashi Toshiaki
Hiroshi Yamashita
Teruyuki Hayashi
Masato Tanaka
Source :: Chemistry Letters. 17:1411-1414
Publication Year :: 1988
Publisher :: The Chemical Society of Japan, 1988.
Abstract: Reductive elimination of cis-bis(phenyldimethylsilyl)bis(phosphine)platinum(II) complexes was found to occur to give sym-diphenyltetramethyldisilane together with redistribution by-products. Addition of free phosphine was favorable for the reductive elimination, and the disilane was formed in more than 80% yields.

Subjects :: chemistry.chemical_compound
chemistry
Chemical reduction
chemistry.chemical_element
Organic chemistry
Redistribution (chemistry)
General Chemistry
Disilane
Platinum
Medicinal chemistry
Reductive elimination
Chemical decomposition
Phosphine

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