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Electrical properties of a single lithium-ion conductor PMSEO-PLPMS

Authors :
Yanguang Ma
Yingyan Jiang
Xuejie Huang
Liquan Chen
Hong Huang
Rongjian Xue
Shibi Fang
Yongjun Li
Source :
Solid State Ionics. 51:69-73
Publication Year :
1992
Publisher :
Elsevier BV, 1992.

Abstract

The electrical properties of a new polymer-lithium salt complex, methyl siloxane terminated polyethylene oxide (PMSEO)- polymethyl lithium propionate siloxane (PLPMS) have been studied. The temperature dependence of the ionic conductivity obeys the VTF equation. By combining ac-impedance measurement and dc-polarization experiments, the transference number of Li + is determined to be close to 1. Lithium ionic conduction was also confirmed by cyclic voltammetry.

Subjects

Subjects :
chemistry.chemical_classification
Materials science
Inorganic chemistry
Salt (chemistry)
chemistry.chemical_element
General Chemistry
Condensed Matter Physics
Ion
chemistry.chemical_compound
chemistry
Electrical resistivity and conductivity
Siloxane
Polymer chemistry
Propionate
Ionic conductivity
General Materials Science
Lithium
Cyclic voltammetry

Details

ISSN :
01672738
Volume :
51
Database :
OpenAIRE
Journal :
Solid State Ionics
Accession number :
edsair.doi...........86efbe7a76974e645ddd79f94f03c0e5
Full Text :
https://doi.org/10.1016/0167-2738(92)90345-p
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