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Reduction of Ni(ACAC)2Under Carbonylative Conditions: A Suitable Procedure for Small Scale Production of Ni (CO)4

Authors :
Josep M. Moretó
Josep Coll
Francisco Camps
F. Boix
J. Torras
Source :
Synthetic Communications. 17:1149-1153
Publication Year :
1987
Publisher :
Informa UK Limited, 1987.

Abstract

Reduction of diluted solutions of anhydrous Ni(II) acetylacetonate in THF by reducing alkylating agents such as DIBAH, n-Bu Li or PrMgBr in the presence of carbon monoxide gave practically quantitative yields of Ni (CO)4.

Details

ISSN :
15322432 and 00397911
Volume :
17
Database :
OpenAIRE
Journal :
Synthetic Communications
Accession number :
edsair.doi...........872c6b762d97440716b0672a9375e8d5
Full Text :
https://doi.org/10.1080/00397918708063964